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A new focus on the practical applications of dipolar cycloaddition chemistryDipolar cycloaddition chemistry has found many useful synthetic applicationsparticularly with respect to the preparation of compounds with new chiralcenters. This approach toward asymmetric syntheses is of major importance inboth the pharmaceutical and agricultural industries.Synthetic Applications of13Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Productsprovides a comprehensive current reference for the synthesis of complexmolecules based on cycloaddition reactions. Updating Albert Padwa s popular1984 volume this new edition shifts the text s focus from theory structurereactivities and selectivities to synthetic applications. Both carbonyl ylidesand nitronates important members of the 13dipole family that were notreviewed previously are now included.Beyond the ability of the 13dipolar cycloaddition reaction to produceheterocycles its importance extends to two other area of organic synthesisboth of which are included in the current volume. First the heteroatomcontaining cycloadducts may be transformed into a variety of otherfunctionalized organic molecules whether cyclic or acyclic. Second many 13dipolar cycloadditions have the ability to generate rings and thefunctionality derived from transformations of such rings containing severalcontiguous stereocenters in one synthetic operation. The authors deal withrelative stereocontrol in 13dipolar cycloadditions in detail. Asymmetricversions of these dipolar cycloadditions represent an entirely new aspect ofthis new edition.Chemists pharmaceutical agricultural and industrialprofessionals as well asindividual researchers will find Synthetic Applications to be an invaluableaddition to the organic chemical literature. «
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